[1,2]-Wittig rearrangement of acetals. Part 2. The influence of reaction conditions

Authors
Gartner, P Letschnig, MF Knollmuller, M Mereiter, K
Citation
P. Gartner et al., [1,2]-Wittig rearrangement of acetals. Part 2. The influence of reaction conditions, TETRAHEDR-A, 11(4), 2000, pp. 1003-1013
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
11
Issue
4
Year of publication
2000
Pages
1003 - 1013
Database
ISI
SICI code
0957-4166(20000310)11:4<1003:[ROAP2>2.0.ZU;2-N
Abstract
Acetals of seven alcohols with (+)-camphor derived enantiomerically pure 7, 8,8-trimethyl-4,7-methanobenzofuran-2-ol were subjected to different reacti on conditions favorable for a [1,2]-Wittig rearrangement. Results with rega rd to conversion, yield and stereochemical course depending on the reaction conditions are discussed. (C) 2000 Elsevier Science Ltd. All rights reserv ed.