The new organometallic rhodium-iron homogeneous catalytic system for hydroformylation

Authors
Trzeciak, AM Mieczynska, E Ziolkowski, JJ
Citation
Am. Trzeciak et al., The new organometallic rhodium-iron homogeneous catalytic system for hydroformylation, TOP CATAL, 11(1-4), 2000, pp. 461-468
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
TOPICS IN CATALYSIS
ISSN journal
10225528 → ACNP
Volume
11
Issue
1-4
Year of publication
2000
Pages
461 - 468
Database
ISI
SICI code
1022-5528(2000)11:1-4<461:TNORHC>2.0.ZU;2-V
Abstract
The addition of Fe(CO)(5) to the systems with [Rh(acac)(CO)L] complexes (L = PPh3, P(OPh)(3), P(NC4H4)(3)) as catalyst precursors caused the increase of aldehydes yield in 1-hexene hydroformylation reaction (80 degrees C, 10 atm) up to 71%. The IR and H-1 NMR measurements confirm the formation of an unstable bimetallic intermediate, [(H)(PPh3)(3)Rh(mu-CO)(2)Fe(CO)(4)], cha racterized with nu(CO) at 1749 cm(-1) and hydrido signal at delta -15.8 ppm .