S. Waplak et al., A STUDY OF THE X-IRRADIATED CS5H3(SO4)(4)CENTER-DOT-H2O CRYSTAL BY EPR IN THE 80-415 K TEMPERATURE-RANGE, Journal of physics. Condensed matter, 9(23), 1997, pp. 4813-4821
The EPR spectra of the x-irradiated fast proton conductor Cs5H3(SO4)(4
) . H2O were investigated in the temperature range of 80-415 K. Two ki
nds of paramagnetic SO4- centres with different proton configurations
below about 370 K and freeze-out behaviour of one of them below about
200 K were observed. The role of acid proton dynamics with respect to
the glassy-like transition is discussed.