Early-stage reactions of Portland cement are markedly influenced by the pre
sence of sucrose. Compositional variations in the aqueous phase are present
ed with some accompanying microstructural and physical delta for sucrose co
ncentrations ranging from 0.1% to 2.0% by weight of cement. Approximately 5
0-80% of the sucrose was consumed in the initial 30 min of hydration and is
assumed to be incorporated into a gel-like reaction product. Aqueons-phase
analysis suggests the gel-like material to be a calcium aluminosulphate pr
obably incorporating silicate ions. Increased addition of sucrose significa
ntly, modified the reaction, as did delayed addition.