A high-nuclearity Ni-Sb carbonyl cluster displaying unprecedented metal stereochemistries: synthesis and X-ray structure of [NEt4](6)[Ni31Sb4(CO)(40)]center dot 2 Me2CO

Authors
Femoni, C Iapalucci, MC Longoni, G Svensson, PH
Citation
C. Femoni et al., A high-nuclearity Ni-Sb carbonyl cluster displaying unprecedented metal stereochemistries: synthesis and X-ray structure of [NEt4](6)[Ni31Sb4(CO)(40)]center dot 2 Me2CO, CHEM COMMUN, (8), 2000, pp. 655-656
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
2000
Pages
655 - 656
Database
ISI
SICI code
1359-7345(2000):8<655:AHNCCD>2.0.ZU;2-Y
Abstract
The mild oxidation of [NEt4](2)[Ni15Sb(CO)(24)] in acetone solution with Sb Cl3 in a ca. 3 : 1 molar ratio leads to the new high-nuclearity [Ni31Sb4(CO )(40)](6-) hexaanion, which displays two interstitial Ni and four semi-inte rstitial Sb atoms with unprecedented stereochemistries.