Characterisation and kinetic behaviour of H2Rh(PPh3)(2)(mu-Cl)(2)Rh(PPh3)(alkene) and related binuclear complexes detected during hydrogenation studies involving parahydrogen induced polarisation

Authors
Colebrooke, SA Duckett, SB Lohman, JAB
Citation
Sa. Colebrooke et al., Characterisation and kinetic behaviour of H2Rh(PPh3)(2)(mu-Cl)(2)Rh(PPh3)(alkene) and related binuclear complexes detected during hydrogenation studies involving parahydrogen induced polarisation, CHEM COMMUN, (8), 2000, pp. 685-686
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
2000
Pages
685 - 686
Database
ISI
SICI code
1359-7345(2000):8<685:CAKBOH>2.0.ZU;2-Q
Abstract
When parahydrogen induced polarisation is used to examine hydrogenation rea ctions involving [Rh(mu-Cl)(PPh3)(2)](2) and RhCl(CO)(PMe3)(2), binuclear d ihydride complexes are detected, characterised, and shown to be capable of alkene hydrogenation.