Kinetics of collision processes in dilute noble gases

Authors
Citation
R. Kalus, Kinetics of collision processes in dilute noble gases, COLL CZECH, 65(2), 2000, pp. 141-160
Citations number
25
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
65
Issue
2
Year of publication
2000
Pages
141 - 160
Database
ISI
SICI code
0010-0765(200002)65:2<141:KOCPID>2.0.ZU;2-A
Abstract
Kinetics of collision processes is analyzed for dilute noble gases within a linear approximation. Dilute gas is treated as a chemically reacting mixtu re of dimers and monomers. Two elementary reaction models are analyzed empl oying theoretical rate constants calculated recently from quasiclassical tr ajectories. Stability of stationary states and relaxation of small concentr ation perturbations are treated in terms of linearized kinetic equations. T he results obtained are generalized for heavier noble gases (neon to xenon) . Helium is, because of quantum nature, analyzed separately.