In this work we briefly review the use of the function L(r), which is defin
ed as minus the Laplacian of the electron density, V(2)p, in the context of
the theory of 'atoms in molecules'. The topology of L(r) can be almost fai
thfully mapped onto the electron pairs of the VSEPR model, The computation
of the gradient vector field L(r) opens new avenues for the further quantif
ication of this mapping. Although major questions are still outstanding thi
s contribution explores for the first time the full topology of L(r) for a
molecule. In water there are four regions: the Core Shell Charge Concentrat
ion (CSCC), the Core Shell Charge Depletion (CSCD), the Valence Shell Charg
e Concentration (VSCC) and the Valence Shell Charge Depletion (VSCD). Each
region has a set of L(r) critical points coagulating in a graph, except the
CSCC. In analogy with the topology of the electron density we propose the
term basin interaction line for the pair of gradient paths linking two basi
ns in L(r), and the term interbasin surface for the surface separating two
basins. We present a systematic study of the water molecule, which possesse
s 43 critical points in L(r). The question is raised how a basin in L(r) ca
n be linked with the domain of the VSEPR model. (C) 2000 Elsevier Science S
.A. All rights reserved.