Hydrolysis and oxidation of an epoxy resin in sub- and supercritical water

Citation
C. Fromonteil et al., Hydrolysis and oxidation of an epoxy resin in sub- and supercritical water, IND ENG RES, 39(4), 2000, pp. 922-925
Citations number
11
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
39
Issue
4
Year of publication
2000
Pages
922 - 925
Database
ISI
SICI code
0888-5885(200004)39:4<922:HAOOAE>2.0.ZU;2-5
Abstract
Hydrolysis and oxidation in sub- and supercritical water has been widely st udied as methods to convert organic wastes into carbon dioxide and water. T his technique could be applied to destroy epoxy resin, a polymer easily use d in nuclear plants. This paper deals with the behavior of an epoxy resin t ested in a batch reactor. The organic network is hydrolyzed and oxidized. T he influence of temperature, pressure, and residence time is studied. Low-m olecular-degradation compounds are characterized by the GC/MS technique. Th e epoxy resin is completely destroyed by way of oxidation at 410 degrees C and 24 MPa.