Synthesis of Cl2InN3, Br2InN3, and related adducts

Authors
Steffek, C McMurran, J Pleune, B Kouvetakis, J Concolino, TE Rheingold, AL
Citation
C. Steffek et al., Synthesis of Cl2InN3, Br2InN3, and related adducts, INORG CHEM, 39(7), 2000, pp. 1615
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
7
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000403)39:7<1615:SOCBAR>2.0.ZU;2-L
Abstract
The synthesis and properties of the new indium inorganic azides Cl2InN3 and Br2InN3 and corresponding adducts with common Lewis bases such as tetrahyd rofuran (THF) and pyridine are presented. The solid-state molecular structu re of the Cl2InN3(THF)(2) compound reveals a dinuclear [Cl2InN3(THF)(2)](2) complex which incorporates a cyclic In2N2 core formed by bridging azide li gands (see illustration).