STRUCTURAL CHEMISTRY OF ORGANOTIN FERROCENECARBOXYLIC ESTERS .2. THE CRYSTAL-STRUCTURE OF DIBUTYLTIN FERROCENECARBOXYLATE OXIDE

Authors
TAO JX XIAO WJ YANG QC
Citation
Jx. Tao et al., STRUCTURAL CHEMISTRY OF ORGANOTIN FERROCENECARBOXYLIC ESTERS .2. THE CRYSTAL-STRUCTURE OF DIBUTYLTIN FERROCENECARBOXYLATE OXIDE, Journal of organometallic chemistry, 531(1-2), 1997, pp. 223-226
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
531
Issue
1-2
Year of publication
1997
Pages
223 - 226
Database
ISI
SICI code
0022-328X(1997)531:1-2<223:SCOOFE>2.0.ZU;2-O
Abstract
The X-ray analysis confirms dibutyltin ferrocenecarboxylate oxide (IA) adopts an ore-bridging dimer structure mode with four anisobidentate bridging carboxylate groups as ligands and has a planar tortuous ladde r geometry. HA crystallizes in the monoclinic space group P2(1)/c with a = 1403.2(3)pm, b = 1309.3(3)pm, c = 2786.0(6)pm, beta - 102.49(3)de grees and Z = 2. The structure was refined to R = 0.0508 and WR = 0.05 64.