Synthesis of 1-amino-3-(trimethylsilyl)allenes by organocuprate addition to 3-(trimethylsilyl)propyne iminium salts

Authors
Schlegel, J Maas, G
Citation
J. Schlegel et G. Maas, Synthesis of 1-amino-3-(trimethylsilyl)allenes by organocuprate addition to 3-(trimethylsilyl)propyne iminium salts, J PRAK CH C, 342(3), 2000, pp. 235-239
Citations number
18
Categorie Soggetti
Chemistry
Journal title
JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG
ISSN journal
09411216 → ACNP
Volume
342
Issue
3
Year of publication
2000
Pages
235 - 239
Database
ISI
SICI code
0941-1216(2000)342:3<235:SO1BOA>2.0.ZU;2-B
Abstract
1-Dialkylamino-3-(trimethylsilyl)allenes 2a-q were obtained by conjugate ad dition of alkyl, vinyl, aryl, hetaryl, and silyl groups, via the respective organocuprates, to 3-(trimethylsilyl)propyne iminium triflates 1a-d. Simil arly, 2-vinylidene-2,3-dihydro-1,3-benzothiazoles 4a,b were synthesized fro m semicyclic propyne iminium triflates 3a,b and a di-tert-butyl cuprate.