Synthesis of reactive condensation products of acetylacetone and their transformation into deeply coloured methine dyes

Citation
Zj. Zhao et H. Hartmann, Synthesis of reactive condensation products of acetylacetone and their transformation into deeply coloured methine dyes, J PRAK CH C, 342(3), 2000, pp. 249-255
Citations number
28
Categorie Soggetti
Chemistry
Journal title
JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG
ISSN journal
09411216 → ACNP
Volume
342
Issue
3
Year of publication
2000
Pages
249 - 255
Database
ISI
SICI code
0941-1216(2000)342:3<249:SORCPO>2.0.ZU;2-6
Abstract
Starting from acetylacetone 1, boric acid and a diol, or a 2-aminothiazole 16 and perchloric acid several dimethyl-substituted 1,3,2-dioxaborines 5 an d thiazolo[3,2a]-pyrimidinium salts 17, resp., have been prepared and trans formed by raction with 4-N,N-dimethylamino-benzaldehyde 3a or 3-methyl-2-me thylmercapto-benzthiazolium perchlorate 13 into deeply colored polymethine dyes 11, 12, 14, 15, and 18-21, and 23-24 their spectroscopic data were rec orded.