Adsorption of gemini and conventional cationic surfactants onto montmorillonite and the removal of some pollutants by the clay

The adsorption of a series of gemini surfactants, [CnH2n+1N+ (CH3)(2)-CH2CH 2](2) . 2Br(-),where It = 10, 12, 14, and 16, on clay (Na-montmorillonite) from their aqueous solution in 0.01 M KBr and the effect of this adsorption on the removal of 2-naphthol and 4-chlorophenol have been studied, Compare d to those of conventional cationic surfactants with similar single hydroph ilic and hydrophobic groups (CnH2n+1N+(CH3)(3) . Br-, where n = 10, 12, 14, and 16), the molar adsorptions of the gemini and conventional surfactants are almost identical. This indicates that only one of the hydrophilic group s in the gemini molecule is adsorbed onto the clay and that the second hydr ophilic is presumably oriented toward the aqueous phase, in contrast to the adsorption of the conventional surfactants, where the hydrophobic group is oriented toward the aqueous phase. Stability studies on dispersions of cla y treated with the two types of surfactants confirm this. The slight increa se in the moles of surfactant to values above the CEC of the clay with an i ncrease in the carbon number of the hydrophobic chain indicates that adsorp tion through hydrophobic group interaction occurs in addition to the major ion exchange. Adsorption studies of the pollutants onto the clay treated by either the gemini or the conventional surfactants show that the former are both more efficient and more effective at removing the pollutants from the aqueous phase. (C) 2000 Academic Press.