The first synthesis of fluorine-containing indeno [2,1 c][1,2,6]-selenadiazines

Citation
A. Haas et al., The first synthesis of fluorine-containing indeno [2,1 c][1,2,6]-selenadiazines, J FLUORINE, 102(1-2), 2000, pp. 313-316
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
102
Issue
1-2
Year of publication
2000
Pages
313 - 316
Database
ISI
SICI code
0022-1139(200003)102:1-2<313:TFSOFI>2.0.ZU;2-K
Abstract
4-Trifluoromethyl-4a-chloro-5,6,7, 8,9,9-hexafluoro(4aH, 9H)indeno[2,1c][1, 2,6] -selenadiazine (1) has been synthesised by the interaction of 2-amino- 3-(1-imino-2,2,2-trifluoroethyl)hexafluoroindene (2) with SeCl4 in the pres ence of HCl accepters. Hydrolysis and reaction with CF3SO3H are also descri bed. Arrangement of atoms for 1 are provided. (C) 2000 Elsevier Science S.A . All rights reserved.