W. Bu et Ai. Isayev, PREPREGS AND LAMINATES OF POLYETHERIMIDE-REINFORCED BY A THERMOTROPICLCP, Journal of applied polymer science, 65(2), 1997, pp. 329-340
Unidirectional sheets (prepregs) of blends of polyetherimide (PEI) wit
h a Liquid crystalline polymer (LCP) are prepared. The mechanical prop
erties of prepregs at directions of 0 degrees, 45 degrees, and 90 degr
ees to the machine direction are investigated as a function of draw ra
tio and LCP concentration. The results show that drawing significantly
increases the tensile strength and modulus of prepregs in the machine
direction and only slightly decreases these properties in the transve
rse direction. An increase in the LCP content greatly enhances the ten
sile strength and modulus in the machine direction but decreases these
properties in the 45 degrees and 90 degrees directions. The strain at
break of prepregs decreases with LCP content in all directions tested
. An abrupt drop in the tensile strength, modulus, and strain at break
of prepregs occurs in the 45 degrees and 90 degrees directions when L
CP content reaches 40%. Prepregs are used to manufacture unidirectiona
l and quasi-isotropic laminates. Unidirectional laminates show mechani
cal properties close to those of the corresponding prepregs. The tensi
le modulus of quasi-isotropic laminates exhibits a continuous increase
with increasing LCP content while the tensile strength increases with
an LCP content up to 30%, then it decreases rapidly. The morphology o
f LCP in prepregs is observed to change from disperse to continuous at
LCP contents of 40 and 50%. This effect is found to be responsible fo
r the large decrease in tensile strength of prepregs in the 45 degrees
and 90 degrees directions and quasi-isotropic laminates at higher LCP
concentration. (C) 1997 John Wiley & Sons, Inc.