Efficient charge separation in C-60-based dyads: Triazolino[4 ',5 ': 1,2][60]fullerenes

Authors
Guldi, DM Gonzalez, S Martin, N Anton, A Garin, J Orduna, J
Citation
Dm. Guldi et al., Efficient charge separation in C-60-based dyads: Triazolino[4 ',5 ': 1,2][60]fullerenes, J ORG CHEM, 65(7), 2000, pp. 1978-1983
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
65
Issue
7
Year of publication
2000
Pages
1978 - 1983
Database
ISI
SICI code
0022-3263(20000407)65:7<1978:ECSICD>2.0.ZU;2-7
Abstract
Triazoline[4,5][60]fullerenes are strong electron accepters that form with tetrathiafulvalene (TTF), a novel type of donor-acceptor dyad exhibiting ef ficient improved electron-transfer dynamics. In particular, a rapid photoin duced intramolecular electron transfer, forming a charge-separated state, i s followed by a slow charge recombination to generate the fullerene triplet excited state in moderate quantum yields.