This paper discusses the development of rubber compounds for air-conditioni
ng hoses designed to meet the stringent demands of the automotive industry,
The phasing out of chlorofluorocarbons (CFCs) as automotive refrigerants a
nd the introduction of new refrigerant fluids requires a new approach to co
mpounding.
The paper focuses on halobutyl formulations for an inner tube based on a VW
draft specification for the temperature range of 90 to 110 degrees C.
The results given in this paper are the optimised rubber compounds and cove
r only part of an extensive study. In the search for an optimum compound, a
study was made of the effect of the polymers, fillers and vulcanisation sy
stem on each of the properties required and particularly on the compression
set. Chlorobutyl and bromobutyl rubber are shown to be excellent base mate
rials for rubber compounds for automotive air conditioning systems. Vulcani
sates based on these elastomers, when correctly compounded, meet the most s
tringent specification requirements.