Some contributions to the understanding of the accelerating system during natural rubber vulcanization - I. Behavior of sulfenamide

Citation
S. Borros et N. Agullo, Some contributions to the understanding of the accelerating system during natural rubber vulcanization - I. Behavior of sulfenamide, KAUT GUM KU, 53(3), 2000, pp. 131-136
Citations number
17
Categorie Soggetti
Material Science & Engineering
Journal title
KAUTSCHUK GUMMI KUNSTSTOFFE
ISSN journal
09483276 → ACNP
Volume
53
Issue
3
Year of publication
2000
Pages
131 - 136
Database
ISI
SICI code
0948-3276(200003)53:3<131:SCTTUO>2.0.ZU;2-R
Abstract
A method based on the modeling approach has been developed for the study of Natural Rubber vulcanization using two different accelerating systems, Squ alene has been chosen as the model compound, The main reaction paths follow ed by sulfenamide (N-cyclohexylamine-2-benzothiazole, CBS) during the first stages of the process have been studied, In all cases, the active role of ZnO and the olefinic chain has been established.