Modification of beta-cyclodextrin with ferrocenyl groups by ring opening of an encapsulated [1]ferrocenophane

Authors
Ferreira, P Goncalves, IS Pillinger, M Rocha, J Santos, P Teixeira-Dias, JJC
Citation
P. Ferreira et al., Modification of beta-cyclodextrin with ferrocenyl groups by ring opening of an encapsulated [1]ferrocenophane, ORGANOMETAL, 19(8), 2000, pp. 1455-1457
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
8
Year of publication
2000
Pages
1455 - 1457
Database
ISI
SICI code
0276-7333(20000417)19:8<1455:MOBWFG>2.0.ZU;2-D
Abstract
beta-Cyclodextrin covalently grafted with ferrocenyl groups is obtained aft er formation of a 2:1 (host to guest) complex between beta-CD and (1,1'-fer rocenediyl)dimethylsilane. Structural investigation in the solid state conf irms -OH attack of the strained C-Si-C bridge to form an O-Si bond.