Reptation in polyethylene-melts with different molecular weights

It is known since a decade that polyethylene shows a characteristic deviati on from the Rouse dynamics, i.e. pronounced entanglement effects, now obser vable in neutron spin-echo (NSE) spectroscopy as a plateau at high Fourier times t. Earlier spin-echo data were limited to t = 20-40 ns and could only determine entanglement distances but not decide between competing models. The now available time range up to 200 ns and more at the IN15 (ILL) NSE sp ectrometer allowed to distinguish the various models and to decide in favou r of de Gennes' Reptation model. In this model the restriction of motion or iginates from a trapping of the chains in a virtual tube. We present a seri es of new NSE-data from PE-melts at 509 K with different molecular weights between M-w = 12 000 g/mol and M-w = 190 000 g/mol extending to 170 ns that allow for the first time a systematic investigation of the reptation dynam ics of PE-melts over a wide range of molecular weights. (C) 2000 Elsevier S cience B.V. All rights reserved.