Coherent proton tunneling in a short hydrogen bonded chain

Citation
Pm. Tomchuk et Sp. Lukyanets, Coherent proton tunneling in a short hydrogen bonded chain, PHYS ST S-B, 218(1), 2000, pp. 291-294
Citations number
25
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICA STATUS SOLIDI B-BASIC RESEARCH
ISSN journal
03701972 → ACNP
Volume
218
Issue
1
Year of publication
2000
Pages
291 - 294
Database
ISI
SICI code
0370-1972(200003)218:1<291:CPTIAS>2.0.ZU;2-I
Abstract
We suggest a possible mechanism of polarization oscillations of a short hyd rogen bonded chain. This mechanism is given rise to a coherent proton tunne lling along hydrogen bonds and/or around heavy atoms. Such oscillations are similar to the effect of coherent spin tunneling which was observed in sma ll magnetic grains and mesoscopic magnetic molecules. The tunneling frequen cy of these transitions is calculated in the WKB approximation. These tunne l oscillations can be involved into the mechanism of ion transport along a chain without formation and motion of any real defects. The tunneling rate of such a flip-flop process does not depend on temperature. The effect of c oherent tunnel repolarization of a chain can be observed at low temperature s when tunneling processes prevail over thermal activation ones.