The S-3(1)-D-3(1) mixing angle for nucleon-nucleon scattering epsilon(1) is
calculated to next-to-next-to-leading order in an effective field theory w
ith perturbative pions. Without pions, the low energy theory fits the obser
ved epsilon(1) well for momenta less than similar to 50 MeV. Including pion
s perturbatively significantly improves the agreement with data for momenta
up to similar to 150 MeV with one less parameter. Furthermore, for these m
omenta the accuracy of our calculation is similar to an effective field the
ory calculation in which the pion is treated nonperturbatively. This gives
phenomenological support for a perturbative treatment of pions in low energ
y two-nucleon processes. We explain why it is necessary to perform spin and
isospin traces in d dimensions when regulating divergences with dimensiona
l regularization in higher partial wave amplitudes.