Width of metastable region in salt solutions

Authors
Citation
Eb. Treivus, Width of metastable region in salt solutions, RUS J AP CH, 72(11), 1999, pp. 1873-1879
Citations number
24
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
72
Issue
11
Year of publication
1999
Pages
1873 - 1879
Database
ISI
SICI code
1070-4272(199911)72:11<1873:WOMRIS>2.0.ZU;2-N
Abstract
The equation for the rate of crystal nucleation in solutions is generalized to the case of crystal hydrate formation. An expression is proposed for th e limiting supersaturation corresponding to the inflection point of the nuc leation rate-supersaturation curve. The dependence of the width of the meta stable region in aqueous solutions on specific free surface energy is consi dered for the case of solution concentration and nucleus entropy fluctuatio ns.