On phase relations, transport properties and defect structure in mixed conducting SrFe1.5-xCoxOz

Citation
R. Bredesen et T. Norby, On phase relations, transport properties and defect structure in mixed conducting SrFe1.5-xCoxOz, SOL ST ION, 129(1-4), 2000, pp. 285-297
Citations number
33
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
129
Issue
1-4
Year of publication
2000
Pages
285 - 297
Database
ISI
SICI code
0167-2738(200004)129:1-4<285:OPRTPA>2.0.ZU;2-Y
Abstract
The stability of the Sr4Fe6O13 phase, and the phase changes taking place in the presence of Co, an discussed. Reported transport parameters are analys ed and discussed in relation to defects and phase changes in SrFe1.5-xCoxOz . A defect model is suggested that is in qualitative agreement with the obs erved transport parameters. It is suggested that defect ordering due to Co2 + ions is decisive for the transport properties. (C) 2000 Elsevier Science B.V. All rights reserved.