A new path for the reductive cleavage of Te-Te bond by the system of Cp2TiCl2/i-BuMgBr and its utility in synthesis of unsymmetrical tellurides

Authors
Huang, X Zheng, WX
Citation
X. Huang et Wx. Zheng, A new path for the reductive cleavage of Te-Te bond by the system of Cp2TiCl2/i-BuMgBr and its utility in synthesis of unsymmetrical tellurides, SYN COMMUN, 30(8), 2000, pp. 1365-1369
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
8
Year of publication
2000
Pages
1365 - 1369
Database
ISI
SICI code
0039-7911(2000)30:8<1365:ANPFTR>2.0.ZU;2-J
Abstract
The cleavage reduction of ditellurides by Cp2TiCl2/i-BuMgBr lead to nucleop hilic tellurides [Cp2TiTeAr]. This species reacts with aliphatic bromides t o give unsymmetrical tellurides in good yield.