Determination of gases (NO, CO, Cl-2) using mixed-mode regimes in the Belousov-Zhabotinskii oscillating chemical reaction

Citation
Pe. Strizhak et Vo. Khavrus, Determination of gases (NO, CO, Cl-2) using mixed-mode regimes in the Belousov-Zhabotinskii oscillating chemical reaction, TALANTA, 51(5), 2000, pp. 935-947
Citations number
30
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
TALANTA
ISSN journal
00399140 → ACNP
Volume
51
Issue
5
Year of publication
2000
Pages
935 - 947
Database
ISI
SICI code
0039-9140(20000428)51:5<935:DOG(CC>2.0.ZU;2-O
Abstract
We show a principle possibility of the determination of gases concentration s (NO, CO, Cl-2) by their affect on mixed-mode oscillations in the Belousov -Zhabotinskii (BZ) oscillating chemical reaction. These oscillations are ch aracterized by single large amplitude oscillation followed by a number of s mall amplitude oscillations. The method of the determination is based on a construction of a calibration plot given by the dependence of the number of small amplitude oscillations on gas concentration. (C) 2000 Elsevier Scien ce B.V. All rights reserved.