Synthesis of optically active 9-oxabicyclo[3.3.1]nona-2,6-diene as a cycloocta-1,5-diene equivalent and the corresponding tetrol

Authors
Takahashi, A Aso, M Tanaka, M Suemune, H
Citation
A. Takahashi et al., Synthesis of optically active 9-oxabicyclo[3.3.1]nona-2,6-diene as a cycloocta-1,5-diene equivalent and the corresponding tetrol, TETRAHEDRON, 56(14), 2000, pp. 1999-2006
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
14
Year of publication
2000
Pages
1999 - 2006
Database
ISI
SICI code
0040-4020(20000331)56:14<1999:SOOA9A>2.0.ZU;2-8
Abstract
Highly enantio- and diastereo-selective synthesis of C-2-symmetric 9-oxabic yclo[3.3.1]nona-2,6-diene and the corresponding C-2-symmetric 2,3,6,7-tetro l has been achieved starting from optically active 5-cyclooctene-1,2-diol p repared by an enzymatic procedure. (C) 2000 Elsevier Science Ltd. All right s reserved.