The phenylthiocyclopropylsilyl group: a useful latent hydroxy group

Authors
Angelaud, R Landais, Y
Citation
R. Angelaud et Y. Landais, The phenylthiocyclopropylsilyl group: a useful latent hydroxy group, TETRAHEDRON, 56(14), 2000, pp. 2025-2036
Citations number
53
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
14
Year of publication
2000
Pages
2025 - 2036
Database
ISI
SICI code
0040-4020(20000331)56:14<2025:TPGAUL>2.0.ZU;2-Q
Abstract
The alpha-dimethyl(1-phenylthio)cyclopropylsilyl group was used as a new ma sked hydroxy group. Three procedures have been devised to allow the oxidati on of this silicon group in the presence of various functionalities. The de sired alcohols are obtained in high yields with retention of configuration at the carbon centre. (C) 2000 Elsevier Science Ltd. All rights reserved.