Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene

Authors
Davies, HML Stafford, DG Hansen, T Churchill, MR Keil, KM
Citation
Hml. Davies et al., Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene, TETRAHEDR L, 41(13), 2000, pp. 2035-2038
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
13
Year of publication
2000
Pages
2035 - 2038
Database
ISI
SICI code
0040-4039(20000327)41:13<2035:EOCSOT>2.0.ZU;2-T
Abstract
Rhodium prolinate catalyzed reactions of diazocarbonyls with cycloheptatrie ne are very dependent on the carbenoid structure and can result in either c yclopropanation, C-H insertion or a combined C-H insertion Cope rearrangeme nt. (C) 2000 Elsevier Science Ltd. All rights reserved.