Electrophilic amination of carbanions by N-carboxamido oxaziridines

Authors
Armstrong, A Atkin, MA Swallow, S
Citation
A. Armstrong et al., Electrophilic amination of carbanions by N-carboxamido oxaziridines, TETRAHEDR L, 41(13), 2000, pp. 2247-2251
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
13
Year of publication
2000
Pages
2247 - 2251
Database
ISI
SICI code
0040-4039(20000327)41:13<2247:EAOCBN>2.0.ZU;2-K
Abstract
A range of 3-aryl-N-carboxamido oxaziridines have been prepared and tested as reagents for electrophilic amination of carbanions. The 3-(2-cyanophenyl )-derivative gave highest yields of amination product, and was used for ami nation of ketone, eater and amide enolates, as well as sulfone-, phosphonat e- and nitrile-stabilized carbanions. (C) 2000 Elsevier Science Ltd. All ri ghts reserved.