STUDY OF IRON-CONTAINING CARBON-SUPPORTED CATALYSTS FOR OXIDATIVE DECOMPOSITION OF HYDROGEN-SULFIDE - THE ACTIVITY-STRUCTURE RELATIONSHIP

Citation
Yv. Maksimov et al., STUDY OF IRON-CONTAINING CARBON-SUPPORTED CATALYSTS FOR OXIDATIVE DECOMPOSITION OF HYDROGEN-SULFIDE - THE ACTIVITY-STRUCTURE RELATIONSHIP, Russian chemical bulletin, 46(1), 1997, pp. 81-85
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
46
Issue
1
Year of publication
1997
Pages
81 - 85
Database
ISI
SICI code
1066-5285(1997)46:1<81:SOICCF>2.0.ZU;2-S
Abstract
Clusters of nonstoichiometric magnetite Fe3O4+delta and pyrrhotite Fe1 -xS were shown to be the active structures of iron-containing carbon-s upported catalysts for oxidative decomposition of hydrogen sulfide. A model of the surface active centers is discussed in terms of the anion vacancies participating in the reaction.