The physical principles of XAFS spectroscopy are given at a sufficiently ba
sic level to enable scientists working in the field of catalysis to critica
lly evaluate articles dealing with XAFS studies on catalytic materials. The
described data-analysis methods provide the basic tools for studying the e
lectronic and structural properties of supported metal, metal-oxide or meta
l-sulfide catalysts. These methods include (a) fitting in R-space, (b) appl
ication of the difference file technique and (c) control of the fit procedu
re with k(1) and k(3) weighting with the help of phase- and amplitude-corre
cted Fourier transforms.