BICYMANTRENYL CHEMISTRY .4. RESOLUTION TO ENANTIOMERS AND DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF BICYMANTRENYLCARBALDEHYDES

Authors
SUPRUNOVICH SV LOIM NM DOLGUSHIN FM YANOVSKY AI GINZBURG AG SOKOLOV VI
Citation
Sv. Suprunovich et al., BICYMANTRENYL CHEMISTRY .4. RESOLUTION TO ENANTIOMERS AND DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF BICYMANTRENYLCARBALDEHYDES, Russian chemical bulletin, 46(1), 1997, pp. 154-158
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
1
Year of publication
1997
Pages
154 - 158
Database
ISI
SICI code
1066-5285(1997)46:1<154:BC.RTE>2.0.ZU;2-W
Abstract
Planar chiral 2- and 3-bicymantrenylcarbaldehydes can be resolved to e nantiomers through Schiff's bases with (S)-(-)-alpha-phenylethylamine. Optically active derivatives of bicymantrenyl with Me and CH2OH subst ituents were synthesized from (-)-3-bicymantrenylcarbaldehyde. The abs olute configuration. of Schiff's base obtained from (+)-3-bicymantreny lcarbaldehyde was determined by X-ray diffraction analysis.