Chains of (4,4 '-bipyridyl)copper(I) bridged by dimolybdate units

Authors
You, WS Wang, EB Xu, L Hu, CW Luan, GY
Citation
Ws. You et al., Chains of (4,4 '-bipyridyl)copper(I) bridged by dimolybdate units, ACT CRYST C, 56, 2000, pp. 289-290
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
3
Pages
289 - 290
Database
ISI
SICI code
0108-2701(200003)56:<289:CO('BB>2.0.ZU;2-L
Abstract
The crystal structure of the title compound, poly[bis[Copper(I)-mu-(4,4'-bi pyridyl)-N:N']-mu-dimolybdato-O:O'] O'], [Cu-2(C10H8N2)(2)(Mo2O7](n), consi sts of (Mo2O7)(2-) units (with the central O atom lying on twofold symmetry axes) and [Cu(4,4'-bipy)](n)(n+) chains (bipy = bipyridyl); the chains are generated by a c-glide-plane operation. The (Mo2O7)(2-) units are covalent ly bridged to two [Cu(4,4'-bipy)](n)(n+) chains, forming a complex with a b ridged double-chain structure. The Cu-O and Cu-N distances are 2.191(3) and 1.933 (3) Angstrom, respectively.