One-dimensional chains in sodium tetraphenylphosphonium bis(2-mercapto-4-methylphenolato-O,S)oxo-vanadate(IV)

Authors
Challen, PR McConville, DB Youngs, WJ
Citation
Pr. Challen et al., One-dimensional chains in sodium tetraphenylphosphonium bis(2-mercapto-4-methylphenolato-O,S)oxo-vanadate(IV), ACT CRYST C, 56, 2000, pp. 310-311
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
3
Pages
310 - 311
Database
ISI
SICI code
0108-2701(200003)56:<310:OCISTB>2.0.ZU;2-R
Abstract
The title compound, Na(C24H20P) [V(C7H6OS)(2)O], contains oxovanadium(IV) i n a square-pyramidal coordination geometry with a basal plane consisting of a cis-S2O2 donor group. The [VO(mmp)(2)](2-) (mmpH(2) = 2-mercapto-4-methy lphenol) units are linked into infinite chains by the sodium ions.