In the present work, Ni-Ce catalyst was used for the preparation of carbon
nanotubes (CNTs) in the atmosphere of partial oxidation of methane (POM). M
ainly growing on quartz wool or wall of reactor, the bulk CNTs were obtaine
d. Probably CNTs were synthesized by two routes due to the typical reaction
conditions of POM, One was that CNTs were produced from the decomposition
of CH4 on the Ni particles. After transported out of the catalyst zone by b
lowing of feedgas, CNTs adhered to quartz wool or the wall of reactor, Pred
ominately, the other way was that. firstly syngas was produced from POM rea
ction and then CNTs grew from disproportionation of CO in presence of hydro
gen. A little remaining oxygen in effluent could remove the other morpholog
ic carbon, so CNTs were easily opened and purified at the same time of grow
th, This research maybe arouse us to assemble the continuous process of POM
and preparation of CNTs, CNTs were applied to be negative materials for li
thium battery. The reversible electrical capacity of simulative lithium bat
tery can be increased ca, 20% with adding 10% (in mass fraction) carbon nan
otubes into natural graphite.