Approximate rydberg states of the hydrogen atom that are concentrated nearKepler orbits

Citation
Ga. Hagedorn et Sl. Robinson, Approximate rydberg states of the hydrogen atom that are concentrated nearKepler orbits, HELV PHYS A, 72(5-6), 1999, pp. 316-340
Citations number
14
Categorie Soggetti
Physics
Journal title
HELVETICA PHYSICA ACTA
ISSN journal
00180238 → ACNP
Volume
72
Issue
5-6
Year of publication
1999
Pages
316 - 340
Database
ISI
SICI code
0018-0238(1999)72:5-6<316:ARSOTH>2.0.ZU;2-D
Abstract
We study the semiclassical limit for bound states of the Hydrogen atom Hami ltonian H(h) = -h(2)/2 Delta - 1/\x\ For each Kepler orbit of the correspon ding classical system, we construct a lowest order quasimode psi(h, x) for H(h) when the appropriate Bohr-Sommerfeld conditions are satisfied. This me ans that psi(h,x) is an approximate solution of the Schrodinger equation in the sense that \\[H(h) - E(h)] psi(h(1))\\ less than or equal to Ch(3/2) \ \psi(h,)\\. The probability density \psi(h, x)\(2) is concentrated near the Kepler ellipse in position space, and its Fourier transform has probabilit y density \psi(h, xi)\(2) concentrated near the Kepler circle in momentum s pace. Although the existence of such states has been demonstrated previousl y, the ideas that underlie our time-dependent construction are intuitive an d elementary.