Synthesis and structure of the pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S) (mu(3)-CO) (mu-CO)(2)(CO)(6)]

Authors
King, JD Mays, MJ McPartlin, M Radojevic, S Sarveswaran, V Solan, GA
Citation
Jd. King et al., Synthesis and structure of the pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S) (mu(3)-CO) (mu-CO)(2)(CO)(6)], INORG CH C, 3(4), 2000, pp. 159-162
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
4
Year of publication
2000
Pages
159 - 162
Database
ISI
SICI code
1387-7003(200004)3:4<159:SASOTP>2.0.ZU;2-6
Abstract
The pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S)(mu(3)-C O)(mu-CO)(2)(CO)(6)] (1) has been synthesised by reaction of [CoMoCp(CO)(7) ] with (BuSSBut)-S-t. X-ray structural analysis identified an asymmetric un it with three cobalt atoms and one molybdenum forming an irregular tetrahed ron while one cobalt-molybdenum edge is bridged by a cobalt atom. Crystal d ata: space group P2(1)/n, a = 10.162(2), b = 13.722(3), c= 17.69(5) Angstro m, beta = 91.44(2)degrees, Z=4. (C) 2000 Elsevier Science S.A. All rights r eserved.