Synthesis, electrochemistry, Langmuir-Blodgett deposition and photophysicsof metal-coordinated fullerene-porphyrin dyads

Citation
T. Da Ros et al., Synthesis, electrochemistry, Langmuir-Blodgett deposition and photophysicsof metal-coordinated fullerene-porphyrin dyads, J ORGMET CH, 599(1), 2000, pp. 62-68
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
599
Issue
1
Year of publication
2000
Pages
62 - 68
Database
ISI
SICI code
0022-328X(20000409)599:1<62:SELDAP>2.0.ZU;2-P
Abstract
A novel fullerene-Ru-porphyrin conjugate (3b) for Langmuir-Blodgett (LB) fi lm deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these other wise non-polar moieties. The complex can be deposited on solid substrates v ia the LB technique and the films obtained show charge separation upon ligh t irradiation. In addition, a careful cyclic voltammetry study of the compl ex is reported. (C) 2000 Elsevier Science S.A, All rights reserved.