The ability of containerless techniques to access very high liquid temperat
ures, maintain specimen purity, enable control of specimen chemistry and ac
cess the supercooled state has created new opportunities to study high-temp
erature liquids with a very high degree of control. Recently, these have be
en combined with x-ray diffraction at synchrotron sources to provide struct
ural information not previously available. This article reviews and summari
zes recent results obtained from x-ray diffraction on levitated liquid mate
rials in both the normal and supercooled states. In particular, it addresse
s the effects of supercooling on the short-range structure, including inter
atomic distances and coordinations, of several high-temperature molten oxid
es, semiconductors and metallic materials. The properties of these liquids
are discussed in the context of available molecular dynamics simulations an
d thermophysical property data.