Highly branched polyethylene graft copolymers prepared by means of migratory insertion polymerization combined with TEMPO-mediated controlled radicalpolymerization
M. Baumert et al., Highly branched polyethylene graft copolymers prepared by means of migratory insertion polymerization combined with TEMPO-mediated controlled radicalpolymerization, MACRO RAPID, 21(6), 2000, pp. 271-276
New families of highly branched polyethylenes containing alkyl short chains
branches as well as polar and non-polar long-chain branches were prepared
by combining migratory insertion copolymerization with controlled radical g
raft copolymerization. Key intermediate was a novel alkoxyamine-functionali
zed 1-alkene which was copolymerized with ethylene using a palladium cataly
st. The resulting highly branched polyethylene with alkoxyamine-functionali
zed short chain branches was used as macroinitiator to initiate controlled
radical graft copolymerization of styrene and styrene/acrylonitrile. Novel
polyethylene graft copolymers with molecular masses of Mw > 100 000 g/mol a
nd narrow polydispersities were obtained. Transmission electron microscopic
studies (TEM) and the presence of two glass transition temperatures at -67
and +100 degrees C indicated microphase separation.