The CMBR Spectrum has been measured by the COBE-FIRAS experiment. Upper lim
its only have been found for distortion parameters y and mu: y(up) = 1.5 x
10(-5) and mu(up) = 9 x 10(-5) at 95% of confidence. FIRAS made differentia
l measurements between sky and blackbody calibrator. The knowledge of its e
missivity is important as far as y and mu measurements as concerned. We hav
e re-estimated the XCAL emissivity by using Ray-Tracing techniques. Diffrac
tion problems have been analyzed by a model based on waveguide approximatio
n: it allowed us to define a propagation function tau inside the XCAL V-gro
ove. The emission of the external calibrator distorted with respect to the
Black-Body emission may result in lower upper limits to y and mu. New upper
limits for distortion parameters y and mu have been calculated considering
the new XCAL emissivity. The results are: y(up) = 3.1 x 10(-5) and mu(up)
= 4.5 x 10(-4) at 95% of confidence. (C) 2000 Elsevier Science B.V. All rig
hts reserved.