Py. Chevalier et al., GLOBAL THERMODYNAMIC APPROACH OF THE MOLTEN CORE-CONCRETE INTERACTION(MCCL) AND SELECTED APPLICATIONS IN THE NUCLEAR-FIELD, Journal de chimie physique et de physico-chimie biologique, 94(5), 1997, pp. 849-860
As part of a study on nuclear reactor safety, we modelled the thermody
namical properties of a complex mixture called ''corium'' obtained in
the unlikely event of a severe accident in a nuclear power plant, if t
he reactor core melts through the vessel and slumps into the concrete
reactor cavity. When the core and the concrete interact, the phenomeno
n is called ''Molten Core-Concrete Interaction'' (MCCI). The equilibri
um state of the cerium is calculated by the GEMINI2 program linked to
the database TDBCR, which includes the thermochemical properties of th
e main constituents of the different materials present in a pressurize
d water reactor. The methodology of assembling a self-consistent datab
ase and some selected applications are presented. Such an approach is
essential to increase the knowledge base of the material ''corium'' to
feed other codes assigned to nuclear reactor safety.