Citation
Y. Gao et al., Active catalyst for the hydrodechlorination of perchlorobenzene, REACT FUNCT, 44(1), 2000, pp. 65-69
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
REACTIVE & FUNCTIONAL POLYMERS
ISSN journal
13815148
→ ACNP
Volume
44
Issue
1
Year of publication
2000
Pages
65 - 69
Database
ISI
SICI code
1381-5148(20000414)44:1<65:ACFTHO>2.0.ZU;2-X
Abstract
Palladium catalysts have been used in the hydrodechlorination of perchlorob
enzene under mild conditions. PdCl2 is not very active for this reaction. H
owever, when PdCl2 is supported on PVP (polyvinyl pyrrolidone), it exhibits
a high activity. Pd-Co supported on PVP displays a bimetallic synergic eff
ect and gives higher catalytic activity. The catalytic activity can be incr
eased further by using NaBH4 to reduce the catalyst instead of H-2 prior to
use. (C) 2000 Elsevier Science B.V. All rights reserved.