Iodo-acetamides by solvolytic addition of iodine in acetonitrile

Authors
Enescu, L Chiraleu, F Draghici, C Ghenciulescu, A
Citation
L. Enescu et al., Iodo-acetamides by solvolytic addition of iodine in acetonitrile, REV RO CHIM, 44(4), 1999, pp. 327-331
Citations number
14
Categorie Soggetti
Chemistry
Journal title
REVUE ROUMAINE DE CHIMIE
ISSN journal
00353930 → ACNP
Volume
44
Issue
4
Year of publication
1999
Pages
327 - 331
Database
ISI
SICI code
0035-3930(199904)44:4<327:IBSAOI>2.0.ZU;2-H
Abstract
The formation of iodo-acetamides by the addition of iodine to benzonorborna diene (1), endo- (2) and exo-benzocyclobuteno-norbornene (3), in acetonitri le solution, in the presence of periodic acid was described. This solvolyti c addition occurs with skeletal rearrangement. Unusual rearrangement from e xo- to endo-benzocyclobuteno-norbornene derivative was observed.