M. Maret et al., NEW METASTABLE ORDERED STRUCTURES IN EPITAXIAL CO-(PT,RU) ALLOY-FILMS, Journal de chimie physique et de physico-chimie biologique, 94(5), 1997, pp. 1063-1068
The preparation of Co-based alloy thin films by Molecular Beam Epitaxy
(MBE) gives rise to a new class of materials that present long-range
ordered structures or atomic stackings quite different from those obse
rved in bulk equilibrium systems. These new materials are interesting
for their magnetic properties, namely in some cases, their high magnet
ocrystalline energy develops a perpendicular anisotropy, a property wh
ich is required for magneto-optic recording. The occurrence of these n
ew structures, that are metastable, is strongly dependent on the natur
e and symmetry of the substrate, on the growth temperature and on depo
sition rates. A general view of results obtained in Co-Pt and Co-Ru sy
stems will be presented and the physical origin of these new structure
s will be discussed.