ACTIVITY MEASUREMENT OF LIQUID ZN-BI ALLOYS BY EMF METHOD

Authors
KATAYAMA I SOMMER F HATTORI Y LIDA T
Citation
I. Katayama et al., ACTIVITY MEASUREMENT OF LIQUID ZN-BI ALLOYS BY EMF METHOD, Journal de chimie physique et de physico-chimie biologique, 94(5), 1997, pp. 1094-1100
Citations number
14
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
94
Issue
5
Year of publication
1997
Pages
1094 - 1100
Database
ISI
SICI code
Abstract
E.M.F. of galvanic cell (-)W\Zn,ZnO\ZrO2(+Y2O3)\Zn-Bi,ZnO\W(+) was mea sured to determine the activity of zinc in the whole composition range at 750-950K for liquid Zn-Bi alloys. The activity of zinc in the allo ys shows large positive deviations from Raoult's law. From the activit y data the concentration fluctuations at long wave length limit Scc(0) are calculated and compared with the model calculation for demixing l iquid binary alloy. The miscibility gap are derived from E vs T plot.