CdS layers were grown by MOVPE on (100) GaAs and (211)B GaAs substrates. Th
e last substrate orientation yields homogeneous wurtzite CdS layers with sh
arply defined free excitonic structures seen in optical reflectivity and ph
otoluminescence. Free exciton luminescence dominates the spectrum at T > 50
K. Structural studies indicate that the layers grown on (100) GaAs substra
tes are a mixture of hexagonal and cubic CdS phases spatially arranged in a
quasi-periodic fashion. The luminescence spectrum reflects this situation.