A new type of aluminum sensor with auxiliary electrode (Al2O3 + Na3AlF6) ha
s been developed, which can be used to measure the aluminum concentrations
of molten steel in the temperature range 1823 to 1873 K. The measured EMFs
reached stable values within 10 s after immersion of the aluminum probe int
o the melt and were nearly independent of the experimental temperature. The
relation between measured EMFs and aluminum activities is in good agreemen
t with the theoretical calculation. The aluminum concentrations in steel me
lt, calculated based on the experimental results, highly approaches those o
btained from chemical analysis. This type of aluminum probe with rapid resp
onse and good accuracy is very promising to be put into practical use of st
eelmaking process control. (C) 2000 Elsevier Science S.A. All rights reserv
ed.